Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride - Names and Identifiers
Name | Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride
|
Synonyms | (S)-RuCl[(p-cyMene)(DM-SEGPHOS)]Cl [RUCL(P-CYMENE)((S)-DM-SEGPHOS)]CL [RuCl(p-cymene)((S)-dm-segphos[R])]Cl [RuCl(p-cymene)((S)-dm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dm-segphos(R))]Cl
|
CAS | 944451-31-4
|
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride - Physico-chemical Properties
Molecular Formula | C56H56Cl2O4P2Ru
|
Molar Mass | 1026.98 |
Melting Point | >100°C |
Water Solubility | Insoluble in water |
Appearance | Powder |
Color | orange to brown |
Storage Condition | 2-8°C |
Sensitive | air sensitive |
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride - Risk and Safety
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride - Introduction
Chloro{(S)-(-)-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride is a compound containing a ruthenium chloride ion. The following is a description of some properties, uses, preparation and safety information about this compound:
Nature:
-Chemical formula: C31H30Cl2O2P2Ru
-Molecular weight: 725.97g/mol
-Appearance: White crystal
-Melting point: 132-134°C
-Solubility: Soluble in anhydrous ether and organic solvents, such as toluene and dichloromethane.
Use:
- Chloro{(S)-(-)-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are usually used as catalysts and have a wide range of applications in organic synthesis, especially in asymmetric synthesis. It can be used to catalyze asymmetric hydrogenation, asymmetric reduction, asymmetric nucleophilic substitution and asymmetric oxidation.
Preparation Method:
- Chloro{(S)-(-)-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride can be obtained by a two-step synthesis. First, (S)-5,5 ′-bis [di (3,5-xylyl) phosphino]-4,4 ′-bis-1, 3-benzodioxazole is reacted with p-tolylruthenium chloride in an organic solvent to form a coordination complex of an organic ligand. Then, by adding ruthenium chloride ions, the final compound is obtained.
Safety Information:
- Chloro{(S)-(-)-5,5 '-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are handled and used with appropriate personal protective measures, such as protective glasses, gloves and laboratory coats.
-This compound has limited specific toxicity data on the human body, so it needs to be used carefully, avoiding direct contact with the skin and inhaling its powder.
-Waste disposal shall comply with local regulations and be thoroughly cleaned or sent to a dedicated waste disposal center for disposal.
Please note that the use and handling of chemical substances in chemical laboratories is dangerous and complex and needs to be carried out under the guidance of professionals.
Last Update:2024-04-10 22:29:15